Unusual coordination mode of tetradentate Schiff base cobalt(III) complexes.

نویسندگان

  • Anish Cyriac
  • Jong Yeob Jeon
  • Jobi Kodiyan Varghese
  • Ji Hae Park
  • Soo Young Choi
  • Young Keun Chung
  • Bun Yeoul Lee
چکیده

Contrary to the stereotype, Jacobsen's catalyst, chiral (salcy)Co(III)OAc adopts an unusual binding mode. The tetradentate {ONNO} ligand does not form a square plane but wraps cobalt in a cis-β fashion while acetate is chelating.

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عنوان ژورنال:
  • Dalton transactions

دوره 41 5  شماره 

صفحات  -

تاریخ انتشار 2012